NCERT Solutions | Class 11 Chemistry Chapter 1

NCERT Solutions | Class 11 Chemistry Chapter 1 | Some Basic Concepts of Chemistry 

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry

CBSE Solutions | Chemistry Class 11

Check the below NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry Pdf free download. NCERT Solutions Class 11 Chemistry  were prepared based on the latest exam pattern. We have Provided Some Basic Concepts of Chemistry Class 11 Chemistry NCERT Solutions to help students understand the concept very well.

NCERT | Class 11 Chemistry

NCERT Solutions Class 11 Chemistry
Book: National Council of Educational Research and Training (NCERT)
Board: Central Board of Secondary Education (CBSE)
Class: 11th
Subject: Chemistry
Chapter: 1
Chapters Name: Some Basic Concepts of Chemistry
Medium: English

Some Basic Concepts of Chemistry | Class 11 Chemistry | NCERT Books Solutions

You can refer to MCQ Questions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry to revise the concepts in the syllabus effectively and improve your chances of securing high marks in your board exams.

NCERT Exercises

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 1.

Calculate the molecular mass of the following :
(i) H2o
(ii) CO2
(iii) CH4

Solution.

(i) Molecular mass of H2O :2 × 1 + 1 × 16 = 18u
(ii) Molecular mass of CO2 :1 × 12 + 2× 16 = 44 u
(iii) Molecular mass of CH4 : 12 + 4 × 1 = 16 u

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 2.

Calculate the mass percent of different elements present in sodium sulphate (Na2SO4).

Solution.

Molecular mass of Na2SO4 = 2 × Atomic mass of Na + Atomic mass of S + 4 × Atomic mass of O
= 2 × 23 + 32 + 4 × 16 = 46 + 32 + 64 = 142 u.
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 1

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 3.

Determine the empirical formula of an oxide of iron which has 69.9% iron and 30.1% oxygen by mass.

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 2
Hence, the empirical formula is Fe2CO3

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 4.

Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.

Solution.

(i)
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 5
Hence, 1 mole of C produces 44 g of CO2
(ii)
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 4
Hence, O2 is the limiting reagent.
∵ 32 g O2 reacts with C to produce 44 g of CO2
∵ 16 g O2 reacts with C to produce \(\frac { 44 }{ 32 } \times 16=22g\quad of\quad { CO }_{ 2 }\)

(iii)
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 6
∵ 64 g O2 reacts with C to produce 88 g of CO2
∵ 16 g O2 reacts with C to produce \(\frac { 88 }{ 64 } \times 16 \)= \(22g\quad of\quad { CO }_{ 2 }\)

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 5.

Calculate the mass of sodium acetate (CH3COONa) required to make 500 mL of 0.375 molar aqueous solution. Molar mass of sodium acetate is 82.0245 g mol-1.

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 7

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 6.

Calculate the concentration of nitric acid in moles per litre in a sample which has a density 1-41 g mL-1 and the mass per cent of nitric acid in it being 69%.

Solution.

Mass percent 69 means that 69 g of HNO3 are dissolved in 100 g of the solution.
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 8

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 7.

How much copper can be obtained from 100 g of copper sulphate (CuS04) ?

Solution.

Molar mass of CuSO4 = 63.5 + 32 + 4 × 16 =63.5 + 32 + 64 = 159.5 amu or u
159.5 g of CuSO4 contains copper = 63.5 g
100 g of CuSO4 contains copper = \(\frac { 63.5 }{ 159.5 } \times 100 \) = 39.81 g

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 8.

Determine the molecular formula of an oxide of iron in which the mass per cent of iron and oxygen are 69.9 and 30.1 respectively.

Solution.

For empirical formula, Fe2O3.
Molecular mass of Fe2O3 x 1 = 2 x 56 + 3 x 16 = 112 + 48 = 160
Molecular formula = u (Empirical formula)
∴ \(n=\frac { Molecular\quad mass }{ Empirical\quad formula\quad mass } =\frac { 160 }{ 160 } \Rightarrow n=1\)
∴ Molecular formula = (Fe2O3) x 1 = (Fe2O3)

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 9.

Calculate the average atomic mass of chlorine using the following data.
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 9

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 10

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 10.

In three moles of ethane (C2H6), calculate the following:
(i) Number of moles of carbon atoms.
(ii) Number of moles of hydrogen atoms.
(iii) Number of molecules of ethane.

Solution.

(i) 1 mole of C2H6 contains 2 moles of carbon atoms.
Number of moles of carbon atoms in 3 moles of C2H6 = 3 x 2 = 6
(ii) 1 mole of C2H6 contains 6 moles of hydrogen atoms.
Number of moles of hydrogen atoms in 3 moles of C2H6 = 3 x 6 = 18
(iii) 1 mole of C2H6 = 6.022 x 1023 molecules Number of molecules in 3 moles of C2H6
= 3 x 6.022 x 1023 = 1.807 x 1024 molecules

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 11.

What is the concentration of sugar (C12H22O11) in mol L -1 if its 20 g are dissolved in enough water to make a final volume up to 2 L?

Solution.

The molecular mass of sugar ((C12H22O11) = 12 x 12 + 1 x 22 + 11 x 16 = 144 + 22 + 176 = 342
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 11

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 12.

If the density of methanol is 0.793 kg L-1 what is its volume needed for making 2.5 L of its 0.25 M solution?

Solution.

Moles of methanol present in 2.5 L of 0.25 M solution
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 12
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 13

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 13.

Pressure is determined as force per unit area of the surface. The SI unit of pressure, pascal is 1 Pa = 1 Nm-2. If mass of air at sea level is 1034 g cm-2, calculate the pressure in pascal.

Solution.

Mass of air at sea level = 1034 g cm-2
Acceleration due to gravity, g = 9.8 m s-2
\(Pressure\quad of\quad air=\frac { 1034 }{ 1000 } \times 9.8\times 100\times 100=1.01332\times { 10 }^{ 5 }Pa \)

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 14.

What is the S.I. unit of mass? How is it defined?

Solution.

The S I. unit of mass is kilogram. The amount of matter present in a substance is called mass. The unit of mass kilogram is defined as being equal to the mass of international prototype of the kilogram.

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 15.

Match the following prefixes with their multiplies
Prefixes Multiples
(i) micro 106
(ii) deca 109
(iii) mega 10-6
(iv) giga 10-15
(v) femto 10

Solution.

(i) micro → 10-6
(ii) deca → 10
(iii) mega → 106
(iv) giga → 109
(v) femto → 10-15

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 16.

What do you mean by significant figures?

Solution.

Significant figures : The significant figures in a number are all the certain digits plus one doubtful digit, e.g., 2005 has four significant figures.

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 17.

A sample of drinking water was found to be severely contaminated with chloroform, CHCI3, supposed to be carcinogenic in nature. The level of contamination was 15 ppm (by mass).
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in the water sample.

Solution.

(i) 15 ppm means 15 parts in million (106) parts
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 14
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 15

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 18.

Express the following in the scientific notation:
(i) 0.0048
(ii) 234,000
(iii) 8008
(iv) 500.0
(v) 6.0012

Solution.

(i) 4.8 x 106
(ii) 2.34 x 105
(iii) 8.008 x 103
(iv) 5.00 x 102
(v) 6.0012 x 100 or 6.0012

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 19.

How many significant figures are present in the following?
(i) 0.0025
(ii) 208
(iii) 5005
(iv) 126,000
(v) 500.0
(vi) 2.0034

Solution.

(i) 2
(ii) 3
(iii) 4
(iv) 3
(v) 4
(vi) 5

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 20.

Round up the following upto three significant figures:
(i) 34.216
(ii) 10.4107
(iii) 0.04597
(iv) 2808

Solution.

(i) 34.2
(ii) 10.4
(iii) 0.0460
(iv) 2810 or 2.81 x 103

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 21.

The following data are obtained when dinitrogen and dioxygen react together to form different compounds:
Mass of dinitrogen Mass of dioxygen
(i) 14 g 16g
(ii) 14 g 32 g
(iii) 28 g 32 g
(iv) 28 g 80 g
(a) Which law of chemical combination is obeyed bythe above experimental data? Give its statement.
(b) Fill in the blanks in the following conversions:
(i) 1 km = ……….. mm = ……….. pm
(ii) 1 mg = ……….. kg = ………….. ng
(iii) 1 mL = ………… L = ……………. dm3

Solution.

(a) Law of multiple proportions : This law was proposed by Dalton in 1803. It states that “If two elements can combine to form more than one compound the masses of one element that combine with a fixed mass of the other element are in the ratio of small whole numbers.
Fixing the mass of dinitrogen as 28 g, masses of dioxygen combined will be 32, 64, 32 and 80 g in the given four oxides. These are in the ratio of 2 : 4 : 2 : 5 which is a simple whole number ratio. Hence, the given data obeys the law of multiple proportions.
(b)
(i) 106mm, 1015pm
(ii) 10-6 kg, 106ng
(iii) 10-3 L, 10-3 dm3

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 22.

If the speed of light is 3.0 x 108 m s-1, calculate the distance covered by light in 2.00 ns.

Solution.

Speed of light = 3.0 x 108 m s-1
Distance covered by light in 2.00 ns = 3.0 x 108 x 2 x 10-9 = 6.00 x 10-1 m = 0.600 m

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 23.

In a reaction :A + B2 → AB2
Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B

Solution.

According to the equation, one mole of A reacts with one mole of B and one atom of A reacts with one molecule of B.
(i) B is limiting reagent because 200 molecules of B will react with 200 atoms of A and 100 atoms of A will be left in excess.
(ii) A
(iii) Both will react completely because it is stoichiometric mixture. No limiting reagent.
(iv) B
(v) A

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 24.

Dinitrogen and dihydrogen react with each other to produce ammonia according to the following chemical equation:
N2(g) + H2(g) → 2NH3(g)
(i) Calculate the mass of ammonia produced if 2.00 x 103 g dinitrogen reacts with 1.00 x 103 g of dihydrogen.
(ii) Will any of the two reactants remain unreacted?
(iii) If yes, which one and what would be its mass?

Solution.

The balanced chemical equation is N3 + 3H3 → 2NH3
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 16

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 25.

How are 0.50 mol Na2CO3 and 0.50 M Na2CO3different?

Solution.

1 mol Na2CO3 \(\equiv\) 2 x 23 + 12 + 3 x 16 = 106 g mol-1
0.50 mol Na2CO3 \(\equiv\) 0.50 x 106= 53 g
0.50 M Na2CO3 solution means that 0.50 moles
or 53 g of Na2CO3 are dissolved in 1000 mL of solution.

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 26.

lf ten volumes of dihydrogen gas reacts with five volumes of dioxygen gas, how many volumes of water vapour would be produced?

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 17

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 27.

Convert the following into basic units :
(i) 28.7 pm
(ii) 15.15pm
(iii) 25365 mg

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 18

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 28.

Which one of the following will have largest number of atoms?
(i) 1 g Au(s)
(ii) 1 g Na(s)
(iii) 1 g Li(s)
(iv) 1 g of Cl2(g)

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 19

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 29.

Calculate the molarity of a solution of ethanol in water in which the mole fraction of ethanol is 0.040.

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 20

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 30.

What will be the mass of one 12C atom in g?

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 21

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 31.

How many significant figures should be present in the answer of the following calculations?
(i) \(\frac { 0.02856\times 298.15\times 0.112 }{ 0.5785 } \)
(ii) 5×5.364
(iii) 0.0125 + 0.7864 + 0.0215

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 22

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 32.

Use the data given in the following table to calculate the molar mass of naturally occurring argon isotopes:
NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 23

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 24

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 33.

Calculate the number of atoms in each of the following:
(i) 52 moles of Ar
(ii) 52 u of He
(iii) 52 g of He.

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 25

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 34.

A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38 g carbon dioxide, 0.690 g of water and no other products. A volume of 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g. Calculate
(i) empirical formula,
(ii) molar mass of the gas, and
(iii) molecular formula.

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 26

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 35.

Calcium carbonate reacts with aqueous HCI to give CaCI2 and CO2 according to the reaction,
CaC03(s) + 2HCI(aq) —> CaCI2(aq)+ CO2(g) + H2(s)O(I). What mass of CaC03 is required to react completely with 25 mL of 0.75 M HCI?

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 27

NCERT Solutions for Class 11 Chemistry Chapter 1, Question 36.

Chlorine is prepared in the laboratory by treating manganese dioxide (Mn02) with aqueous hydrochloric acid according to the reaction
4HCI(aq) + MnO2(s) → 2H2O(I) + MnCI2(aq) + Cl2(g)
How many grams of HCI react with 5.0 g of manganese dioxide?

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry 28

NCERT Class 11 Chemistry

Class 11 Chemistry Chapters | Chemistry Class 11 Chapter 1

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