NCERT Solutions | Class 11 Chemistry Chapter 2 | Structure of The Atom

CBSE Solutions | Chemistry Class 11
Check the below NCERT Solutions for Class 11 Chemistry Chapter 2 Structure of The Atom Pdf free download. NCERT Solutions Class 11 Chemistry were prepared based on the latest exam pattern. We have Provided Structure of The Atom Class 11 Chemistry NCERT Solutions to help students understand the concept very well.
NCERT | Class 11 Chemistry
Book: | National Council of Educational Research and Training (NCERT) |
---|---|
Board: | Central Board of Secondary Education (CBSE) |
Class: | 11th |
Subject: | Chemistry |
Chapter: | 2 |
Chapters Name: | Structure of The Atom |
Medium: | English |
Structure of The Atom | Class 11 Chemistry | NCERT Books Solutions
NCERT Exercises
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 1.
(ii) Calculate the mass and charge of one mole of electrons.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 2.
(ii) Find (a) the total number and (b) the total mass of neutrons in 7 mg of 14C. (Assume that mass of a neutron = 1.675 x 10-27kg).
(iii) Find (a) the total number and (b) the total mass of protons in 34 mg of NH3 at STP. Will the answer change if the temperature and pressure are changed?
Solution.


NCERT Solutions for Class 11 Chemistry Chapter 2, Question 3.

Solution.


NCERT Solutions for Class 11 Chemistry Chapter 2, Question 4.
(i) Z= 17, 4 = 35.
(ii) Z= 92, A = 233.
(iii) Z = 4, 4 = 9.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 5.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 6.
(i) corresponds to light of frequency 3 x 1015Hz.
(ii) have wavelength of 0.50 A.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 7.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 8.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 9.
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV = 1.6020 x 10-19 J).
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 10.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 11.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 12.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 13.
Solution.
According to Rydberg equation,
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 14.
Solution.


NCERT Solutions for Class 11 Chemistry Chapter 2, Question 15.
Solution.
\(=\frac { n(n-1) }{ 2 } =\quad \frac { 6(6-1) }{ 2 } =\frac { 30 }{ 2 } =15lines\)NCERT Solutions for Class 11 Chemistry Chapter 2, Question 16.
(ii) Calculate the radius of Bohr’s fifth orbit for hydrogen atom.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 17.
Solution.
According to Rydberg equation,
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 18.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 19.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 20.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 21.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 22.
Na+, K+, Mg2+, Ca2+, S2-, Ar
Solution.
Species Number of electronsNa+ 11 – 1 = 10
K+ 19 – 1 = 18
Mg2+ 12 – 2 = 10
Ca2+ 20 – 2 = 18
S2-, 16 + 2 = 18
Ar = 18
Thus, Na+, K+, Mg2+, Ca2+, S2-, and Ar have the same number of electrons.
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 23.
(a) H–
(b) Na+
(c) O2-
(d) F –
(ii) What are the atomic numbers of elements whose outermost electrons are represented by
(a) 3s-1
(b) 2p3 and
(c) 3p5?
(iii) Which atoms are indicated by the following configurations?
(a) [He] 2s-1
(b) [Ne] 3s23p3
(c) [Ar] 4s23d1.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 24.
Solution.
For g-orbital, l = 4. For a value of n, possible values of l are 0 to n – 1. Thus,l = 4 = n-1 ⇒ n = 5
The lowest value of n that allows y-orbitals to exist is 5.
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 25.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 26.
(i) the number of protons and
(ii) the electronic configuration of the element.
Solution.
Number of electrons = 29, number of neutrons = 35(i) We know that Z = c = p
∵ c = 29 ∴ p = 29
(ii) Electronic configuration :
1s22s22p63s23p63d104s1
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 27.
Solution.
Species Number of electro:\({ H }_{ 2 }^{ + }\) 1(1 + 1 – 1 = 1)
H2 2 (1 + 1 =2)
\({ O}_{ 2 }^{ + }\) 15(8 + 8 – 1 = 15)
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 28.
(ii) List the quantum numbers (m, and l) of electrons for 3d orbital.
(iii) Which of the following orbitals are possible?
1 p, 2s, 2p and 3f
Solution.
(i) When n = 3, l = 0, 1, 2When l = 0, m1 = 0. When l = 1, m1 = -1, 0, +1. When l = 2, m1 = -2, -1, 0, +1, +2.
(ii) For 3d-orbital l = 2, m1 = -2, -1, 0, +1, +2
(iii) For a particular value of n, the allowed values of l are 0 to n – 1 only. Hence, 2s and 2p are the only possible orbitals.
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 29.
(a) n = 1, l= 0;
(b) n = 3, l = 1;
(c) n = 4, l = 2;
(d) n = 4, l = 3.
Solution.
(a) 1s(b) 3p
(c) 4d
(d) 4f
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 30.
(a) n = 0, l = 0, m1 = 0, ms = + 1/2
(b) n = 1, l = 0, m1 = 0, ms = -1/2
(c) n= 1, l= 1,m1 = 0, ms = + 1/2
(d) n = 2, l= 1, m1 = 0, ms = -1/2
(e) n = 3, l- 3, m1 = -3, ms = +1/2
(f) n = 3, l= 1, m1 = 0, ms = + 1/2
Solution.
(a) Not possible because n ≠ 0(c) Not possible because when n = 1, l = 0
(e) Not possible because when n = 3, l = 0, 1, 2, and not equal to 3.
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 31.
(a) n = 4,ms = -1/2
(b) n = 3, l=0
Solution.
(a) Total number of electrons in n = 4 is 2n2 = 2(4)2 = 32But half of these electrons have ms = -1/2
∴ Number of electrons = 16
(b) Number of electrons = 2 [ ∵ 3s subshell]
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 32.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 33.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 34.

The ionization energy for the H atom in the ground state is 2.18 x 10-18 J atom-1.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 35.
Solution.
A carbon atom covers length = diameter of atom = 0.15 nm= 0.15 x 10-9 x 102 cm = 0.15 x 10-7 cm
∴ Number of carbon atoms which can be placed on 20 cm length
= \(\frac { 20 }{ 0.15\times { 10 }^{ -7 } } =1.33\times { 10 }^{ 9 }\)
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 36.
Solution.
An atom will cover length equal to its diameter.Diameter of carbon atom = \(\frac { 2.4 }{ 2\times { 10 }^{ 8 } } =1.2\times { 10 }^{ -8 }cm \)
Radius of carbon atom = \(\frac { 1.2\times { 10 }^{ -8 } }{ 2 } \)
= 0.6 x 10-8 cm = 0.6 x 10-8 x 10-2 m
= 0.06 x 10-8 m = 0.06 nm
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 37.
(a) radius of zinc atom in pm and
(b) number of atoms present in a length of 1.6 cm if the zinc atoms are arranged side by side lengthwise.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 38.
Solution.
Charge of one electron = 1.602 x 10-19 CNumber of electrons present = \(\frac { 2.5\times { 10 }^{ -16 } }{ 1.602\times { 10 }^{ -19 } } \)
= 1.56 x 103
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 39.
Solution.
Charge of one electron = -1.602 x 10-19 CNumber ot electrons = \(\frac { -1.282\times { 10 }^{ -18 } }{ -1.602\times { 10 }^{ -19 } } \approx 8.\)
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 40.
been used to be bombarded by the a-particles. If the thin foil of light atoms like aluminium etc. is used, what difference would be observed from the above results?
Solution.
Lesser number of a-particles will be deflected because nucleus of lighter atoms have smaller positive charge on their nuclei.NCERT Solutions for Class 11 Chemistry Chapter 2, Question 41.

Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 42.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 43.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 44.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 45.
(a) radiation from microwave oven
(b) amber light from traffic signal
(c) radiation from FM radio
(d) cosmic rays from outer space and
(e) X-rays.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 46.
Solution.


NCERT Solutions for Class 11 Chemistry Chapter 2, Question 47.
(a) the frequency of emission,
(b) distance travelled by this radiation in 30 s,
(c) energy of quantum and
(d) number of quanta present if it produces 2 J of energy.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 48.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 49.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 50.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 51.
(a) the threshold frequency and
(b) the threshold wavelength of the radiation.
(c) If the caesium elements is irradiated with a wavelength 500 nm, calculate the kinetic energy and the velocity of the ejected photoelectron.
Solution.


NCERT Solutions for Class 11 Chemistry Chapter 2, Question 52.
λ(nm) 500 450 400
v x 105 (m s-1) 2.55 4.35 5.20
Solution.


NCERT Solutions for Class 11 Chemistry Chapter 2, Question 53.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 54.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 55.
represented as \(\upsilon =3.29\times { 10 }^{ 15 }(HZ)\left[ \frac { 1 }{ { 3 }^{ 2 } } -\frac { 1 }{ { n }^{ 2 } } \right] \) Calculate the value of n if the transition is observed at 1285 nm. Find the region of the spectrum.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 56.
Solution.


NCERT Solutions for Class 11 Chemistry Chapter 2, Question 57.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 58.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 59.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 60.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 61.
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 62.
1. n = 4, l = 2, m1 = -2, ms = -1/2
2. n = 3, l = 2, m1= 1, ms =+1/2
3. n = 4, l= 1, m1 = 0, ms = +1/2
4. n = 3, l = 2,m1 = -2, ms = -M2
5. n = 3, l = 1, m1=-1, ms =+1/2
6. n = 4, l = 1, m1 = 0, mss =+1/2
Solution.
1. 4d(n + l = 4 + 2 = 6)2. 3d (n + l = 3 + 2 = 5)
3. 4p (n + l = 4 + 1 = 5)
4. 3d (n + l = 3 + 2 = 5)
5. 3p (n + l = 3 + 1 = 4)
6. 4p (n + l = 4 + 1 = 5)
Greater the value of n + l, higher will be the energy of orbital. If two orbitals have same n + l value then the orbital having higher n value will possess higher energy.
Therefore, the required order is : 5<2 = 4<6 = 3<1
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 63.
Solution.
The electron in 4 p orbital experiences lowest effective nuclear charge because it is farthest from the nucleus.NCERT Solutions for Class 11 Chemistry Chapter 2, Question 64.
(i) 2s and 3s,
(ii) 4d and 4f,
(iii) 3d and 3p.
Solution.
Orbital closer to the nucleus will experience larger effective nuclear charge.(i) 2s
(ii) 4 d
(iii) 3 p
NCERT Solutions for Class 11 Chemistry Chapter 2, Question 65.
Solution.
Si has nuclear charge, Z = 14 while Al has Z = 13. Thus, the electrons of 3p-orbital of Si will experience more effective nuclear charge from the nucleus.NCERT Solutions for Class 11 Chemistry Chapter 2, Question 66.
(a) P,
(b) Si,
(c) Cr,
(d) Fe and
(e) Kr
Solution.

NCERT Solutions for Class 11 Chemistry Chapter 2, Question 67.
(b) How many electrons will be present in the sub-shells having m5 value of -1/2 for n = 4?
Solution.

NCERT Class 11 Chemistry
Class 11 Chemistry Chapters | Chemistry Class 11 Chapter 2
Chapterwise NCERT Solutions for Class 11 Chemistry
-
NCERT Solutions For Class 11 Chemistry Chapter 1 Some Basic Concepts of Chemistry
NCERT Solutions For Class 11 Chemistry Chapter 2 Structure of The Atom
NCERT Solutions For Class 11 Chemistry Chapter 3 Classification of Elements and Periodicity in Properties
NCERT Solutions For Class 11 Chemistry Chapter 4 Chemical Bonding and Molecular Structure
NCERT Solutions For Class 11 Chemistry Chapter 5 States of Matter
NCERT Solutions For Class 11 Chemistry Chapter 6 Thermodynamics
NCERT Solutions For Class 11 Chemistry Chapter 7 Equilibrium
NCERT Solutions For Class 11 Chemistry Chapter 8 Redox Reactions
NCERT Solutions For Class 11 Chemistry Chapter 9 Hydrogen
NCERT Solutions For Class 11 Chemistry Chapter 10 The sBlock Elements
NCERT Solutions For Class 11 Chemistry Chapter 11 The pBlock Elements
NCERT Solutions For Class 11 Chemistry Chapter 12 Organic Chemistry: Some Basic Principles and Techniques
NCERT Solutions For Class 11 Chemistry Chapter 13 Hydrocarbons
NCERT Solutions For Class 11 Chemistry Chapter 14 Environmental Chemistry
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NCERT Solutions for Class 11 All Subjects | NCERT Solutions for Class 9 All Subjects |
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