NCERT Solutions | Class 12 Chemistry Chapter 11

NCERT Solutions | Class 12 Chemistry Chapter 11 | Alcohols Phenols and Ethers 

CBSE Solutions | Chemistry Class 12

Check the below NCERT Solutions for Class 12 Chemistry Chapter 11 Alcohols Phenols and Ethers Pdf free download. NCERT Solutions Class 12 Chemistry  were prepared based on the latest exam pattern. We have Provided Alcohols Phenols and Ethers Class 12 Chemistry NCERT Solutions to help students understand the concept very well.

NCERT | Class 12 Chemistry

NCERT Solutions Class 12 Chemistry

Book:	National Council of Educational Research and Training (NCERT)
Board:	Central Board of Secondary Education (CBSE)
Class:	12th
Subject:	Chemistry
Chapter:	11
Chapters Name:	Alcohols Phenols and Ethers
Medium:	English

Alcohols Phenols and Ethers | Class 12 Chemistry | NCERT Books Solutions

You can refer to MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols Phenols and Ethers to revise the concepts in the syllabus effectively and improve your chances of securing high marks in your board exams.

NCERT Exercises

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 1.

Classify the following as primary, secondary and tertiary alcohols :

Solution.

Primary alcohols : (i), (ii) and (iii)
Secondary alcohols : (iv) and (v)
Tertiary alcohols : (vi)

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 2.

Identify allylic alcohols in the above examples.

Solution.

Allvlir alcohols : (ii) and (vi).

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 3.

Name the following compounds according to IUPAC system.

Solution.

1. 3-Chloromethyl-2-isopropylpentan-l-ol
2. 2, 5-Dimethylhexane-1,3-diol
3. 3-Bromocyclohexanol
4. Hex-l-en-3-ol
5. 2-Bromo-3-methylbut-2-en-1 -ol

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 4.

Show how are the following alcohols prepared by the reaction of a suitable Grignard reagent on methanal.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 5.

Write structures of the products of the following reactions :

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 6.

Give structures of the products you would expect when each of the following alcohol reacts with (a) HCl – ZnCl₂ (b) HBr and (c) SOCl₂.

1. Butan-1-ol
2. 2-Methylbutan-2-ol

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 7.

Predict the major product of acid catalysed dehydration of

1. 1-methylcyclohexanol and
2. butan-1-ol

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 8.

Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the corresponding phenoxide ions.

Solution.

The attachment of the -NO₂ group to the phenol molecule at 0- and p-positions decreases the electron density on oxygen atom. This causes the oxygen atom to pull the bond pair of electrons of the O – H bond towards itself thereby facilitating the release of H as H⁺.

The resonance structures of the phenoxide ions are :

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 9.

Write the equations involved in the following reactions :

1. Reimer-Tiemann reaction
2. Kolbe’s reaction

Solution.

 

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 10.

Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 11.

Which of the following is an appropriate set of reactants for the preparation of 1 -methoxy-4- nitrobenzene and why?

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 12.

Predict the products of the following reactions :

Solution.

NCERT Exercises

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 1.

Write IUPAC names of the following compounds :

Solution.

1. 2,2,4-Trimethylpentan-3-ol
2. 5-Ethylheptan-2,4-diol
3. Butane-2,3-diol
4. Propane-1,2,3-triol
5. 2-Methylphenol
6. 4-Methylphenol
7. 2,5-Dimethylphenol
8. 2,6-Dimethylphenol
9. l-Methoxy-2-methylpropane
10. Ethoxybenzene
11. 1-Phenoxyheptane
12. 2-Ethoxybutane

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 2.

Write structures of the compounds whose IUPAC names are as follows :

1. 2-Methylbutan-2-ol
2. 1-Phenylpropan-2-ol
3. 3,5-Dimethylhexane-1,3,5-triol
4. 2,3-Diethylphenol
5. 1-Ethoxypropane
6. 2-Ethoxy-3-methylpentane
7. Cyclohexylmethanol
8. 3-Cydohexylpentan-3-ol
9. Cyclopent-3-en-1 -ol
10. 3-Chloromethylpentan-1-ol

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 3.

1. Draw the structures of all isomeric alcohols of molecular formula C₅H₁₂O and give their IUPAC names.
2. Classify the isomers of alcohols in question 3 (i) as primary, secondary and tertiary alcohols.

Solution.

The isomeric alcohols with molecular formula C₅H₁₂O are :

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 4.

Explain why propanol has higher boiling point than that of the hydrocarbon, butane.

Solution.

The boiling point of any compound depends on the strength of inter-molecular forces. Stronger is the inter-molecular attraction, higher is the boiling point.

In butane, the molecules interact with each other through weak van der Waals forces. These weak forces can be easily overcome by supplying small amount of heat energy. Thus, they have low boiling point.

In propanol, the molecules are held together by strong hydrogen bonding. These attractive forces operating between molecules are more difficult to break and therefore higher amount of heat needs to be supplied, therefore, the higher boiling point.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 5.

Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses. Explain this fact.

Solution.

Organic compounds are soluble in water if they are able to form hydrogen bonds with it. Alcohols are able to establish this interaction by the virtue of their OH group and are therefore soluble in water. On the other hand, other hydrocarbons of comparable mass do not dissolve in water since they cannot form hydrogen bonds.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 6.

What is meant by hydroboration-oxidation reaction? Illustrate it with an example.

Solution.

Hydroboration-oxidation is a method of preparation of alcohols from alkenes. The main advantage of this method is the high yield of alcohol obtained. During hydroboration, diborane (BH₃)₂ is made to react with an alkene to form an addition product. This product is then treated with hydrogen peroxide in the presence of sodium hydroxide to give alcohol.
For example,

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 7.

Give the structure and IUPAC names of monohydric phenols of molecular formula, C₇H₈O.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 8.

While separating a mixture of ortho and para nitrophenols by steam distillation, name the isomer which will be steam volatile. Give reason.

Solution.

During steam distillation, it is the lower boiling compound which distills out first. Between ortho- and para-nitrophenol it is the ortho-isomer which will be steam volatile since it has a lower boiling point.

The difference in boiling point between the two isomers can be understood based on the structural difference. In ortho-isomer intra¬molecular hydrogen bonding takes place while in the pttra-isomer, inter-molecular hydrogen bonding takes place.

As a result of the strong forces operating between the molecules of p-isomer, the boiling point is higher and it is not steam volatile.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 9.

Give the equations of reactions for the preparation of phenol from cumene.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 10.

Write chemical reaction for the preparation of phenol from chlorobenzene.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 11.

Write the mechanism of hydration of ethene to yield ethanol.

Solution.

The acid catalysed hydration of ethene may be represented as :

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 12.

You are given benzene, cone. H₂SO₄ and NaOH. Write the equations for the preparation of phenol using these reagents.

Solution.

Using the given reagents, phenol may be prepared as :

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 13.

Show how will you synthesise :

1. 1 -Phenylethanol from a suitable alkene.
2. Cyclohexylmethanol using an alkyl halide by an S_N² reaction.
3. Pentan-1-ol using a suitable alkyl halide.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 14.

Give two reactions that show the acidic nature of phenol. Compare acidity of phenol with that of ethanol.

Solution.

The resonance stabilization provided by the contributing structures (I)-(V) more than compensates for the bond breakage energy of O – H bond and thus causes phenol to be acidic in nature.

No such resonance structures are possible for ethoxide ion and therefore the conversion of ethanol to ethoxide is not favoured under normal conditions. Therefore, ethanol is less acidic than phenol.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 15.

Explain why is ortho nitrophenol more acidic than methoxyphenol?

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 16.

Explain how does the -OH group attached to a carbon of benzene ring activates it towards electrophilic substitution.

Solution.

In an electrophilic substitution reaction, an electron deficient species attacks the benzene ring which is e^– rich.

When an -OH group is attached to the benzene ring, by the virtue of its electron releasing nature increases the e^– density of the ring and thus activates it, i.e., makes it a welcome site for electrophiles.

The increase in electron density can be visualised as :

From structures (I) – (V), we find that the attachment of hydroxyl group to benzene has increased the electron density (-ve charge) on the ring carbon atoms (especially C-2, C-4 and C-6). It is therefore said to have activated the ring towards electrophiles which are attracted to the increased electron density.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 17.

Give equations of the following reactions :

1. Oxidation of propan-1 -ol with alkaline KMnO₄ solution.
2. Bromine in CS₂ with phenol.
3. Dilute HNO₃ with phenol.
4. Treating phenol with chloroform in presence of aqueous NaOH.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 18.

Explain the following with an example.
(i) Kolbe’s reaction
(ii) Reimer-Tiemann reaction
(iii) Williamson ether synthesis
(iv) Unsymmetrical ether.

Solution.

(i) Kolbe’s reaction :
The fact that phenoxide ion is even more reactive than phenol towards incoming electrophiles is made use of in this reaction. Sodium phenoxide is reacted with CO₂ followed by acid treatment to yield o-hydroxybenzoic acid as the major product.

(ii) Reimer-Tiemann reaction :
Treatment of phenol with chloroform in the presence of aqueous alkali introduces a CHO group at the ortho position. Acidification yields salicylaldehyde.

(iii) Williamson synthesis :
In this method, an alkyl halides is reacted with sodium alkoxide.
R-X + R’ – ONa → R-O-R’ + NaX
The reaction involves SN2 attack of an alkoxide ion on 1° RX.

(iv) Unsymmetrical ethers :
Unsymmetrical ethers are organic compounds where the ethereal oxygen atom is attached to two different alkyl or aryl groups, e.g.,
C₂H₅ – O – CH₃, C₆H₅O – C₂H₅, etc.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 19.

Write the mechanism of acid dehydration of ethanol to yield ethene.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 20.

How are the following conversions carried out?

1. Propene → Propan-2-ol
2. Benzyl chloride → Benzyl alcohol
3. Ethyl magnesium chloride → Propan-1-ol
4. Methyl magnesium bromide → 2-Methylpropan-2-ol.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 21.

Name the reagents used in the following reactions :

1. Oxidation of primary alcohol to carboxylic acid.
2. Oxidation of primary alcohol to aldehyde.
3. Bromination of phenol to 2,4,6-tribromophenol.
4. Benzyl alcohol to benzoic acid.
5. Dehydration of propan-2-ol to propene.
6. Butan-2-one to butan-2-ol.

Solution.

1. Alkaline KMnO₄
2. Pyridinium chlorochromate in chloromethane (CH₂Cl₂)
3. Br₂/H₂O
4. Alkaline KMnO₄
5. Cone. H₂SO₄ or H₃PO₄ at 433-443 K
6. H₂/Ni or NaBH₄ or LiAlH₄

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 22.

Give reason for the higher boiling point of ethanol in comparison to methoxymethane.

Solution.

The higher boiling point of ethanol may be attributed to the presence of intermolecular hydrogen bonding in it.

Due to such extensive bonding, more energy needs to be supplied to ethanol to break these bonds and move it into the vapour phase.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 23.

Give IUPAC names of the following ethers :

Solution.

1. 1 -Ethoxy-2-methylpropane
2. 2-Chloro-l-methoxyethane
3. 4-Nitroanisole
4. 1-Methoxypropane
5. 1-Ethoxy-4,4-dimethylcyclohexane
6. Ethoxybenzene

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 24.

Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis :

1. 1-Propoxypropane
2. Ethoxybenzene
3. 2-Methyl-2-methoxypropane
4. 1-Methoxyethane

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 25.

Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers.

Solution.

The main limitation of Williamson’s ether synthesis lies in its unemployability for preparation of unsymmetrical ethers where the compound contains secondary or tertiary alkyl groups.

e.g., reaction between tert-butyl bromide and sodium methoxide yields an alkene.

This is because the competing elimination reaction predominates over S_N2 and alkene is formed.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 26.

How is 1-propoxypropane synthesised from propan-1 -ol? Write mechanism of this reaction.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 27.

Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method. Give reason.

Solution.

Consider the reaction between propan- 2-ol molecules in the presence of acid.

If an ether is to be formed, another alcohol molecule must carry out a nucleophilic attack on the carbocation as

However, this does not happen because of
(a) the steric hindrance around the carbocation, and
(b) bulky size of the nucleophile which would further cause crowding.
As a result, the carbocation prefers to lose a proton and forms an alkene.

For the same reason 3° alcohols in the presence of acid do not form ethers since 3° alcohols are even more sterically hindered than 2° alcohols.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 28.

Write the equation of the reaction of hydrogen iodide with :

1. 1-propoxypropane
2. methoxybenzene; and
3. benzyl ethyl ether.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 29.

Explain the fact that in aryl alkyl ethers (i) the alkoxy group activates the benzene ring towards electrophilic substitution and (ii) it directs the incoming substituents to ortho and para positions in benzene ring.

Solution.

Consider the following resonance structures of aryl alkyl ethers :

(i) From the above structures we find that the presence of the OR group has increased the electron density on the benzene ring and therefore the ring is said to have been activated towards incoming electrophiles.

(ii) From structures (II), (III) and (IV) we find that and the electron density has increased on C-2, C-4 and C-6, i.e., at the ortho and para positions. As a result the electrophile (E ) attaches itself to these e- rich sites and the -OR group is said to have directed the E® to ortho and para positions.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 30.

Write the mechanism of the reaction of Hl with methoxymethane.

Solution.

The reaction between methoxymethane and Hl is :

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 31.

Write equations of the following reactions :

1. Friedel-Crafts reaction – alkylation of anisole.
2. Nitration of anisole.
3. Bromination of anisole in ethanoic acid medium.
4. Friedel-Craft’s acetylation of anisole.

Solution.

 

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 32.

Show how would you synthesise the following alcohols from appropriate alkenes.

Solution.

NCERT Solutions for Class 12 Chemistry Chapter 11, Question 33.

When 3-methylbutan-2-ol is treated with HBr, the following reaction takes place :

Give a mechanism for this reaction.
[Hint : The secondary carbocation formed in step II rearranges to a more stable tertiary carbocation by a hydride ion shift from 3rd carbon atom.]

Solution.

NCERT Class 12 Chemistry

Class 12 Chemistry Chapters | Chemistry Class 12 Chapter 11

Chapterwise NCERT Solutions for Class 12 Chemistry

NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions
NCERT Solutions For Class 12 Chemistry Chapter 3 Electro chemistry
NCERT Solutions For Class 12 Chemistry Chapter 4 Chemical Kinetics
NCERT Solutions For Class 12 Chemistry Chapter 5 Surface Chemistry
NCERT Solutions For Class 12 Chemistry Chapter 6 General Principles and Processes of Isolation of Elements
NCERT Solutions For Class 12 Chemistry Chapter 7 The p Block Elements
NCERT Solutions For Class 12 Chemistry Chapter 8 The d and f Block Elements
NCERT Solutions For Class 12 Chemistry Chapter 9 Coordination Compounds
NCERT Solutions For Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ethers
NCERT Solutions For Class 12 Chemistry Chapter 12 Aldehydes Ketones and Carboxylic Acids
NCERT Solutions For Class 12 Chemistry Chapter 13 Amines
NCERT Solutions For Class 12 Chemistry Chapter 14 Biomolecules
NCERT Solutions For Class 12 Chemistry Chapter 15 Polymers
NCERT Solutions For Class 12 Chemistry Chapter 16 Chemistry in Everyday Life

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